In this study, we synthesized a powder consisting of core-shell-structured Ni/NiO nanocluster-decorated graphene (Ni/NiO-graphene) by a simple process for use as an anodic material for lithium-ion batteries. First, a crumpled graphene powder consisting of uniformly distributed Ni nanoclusters was prepared by one-pot spray pyrolysis. This powder was subsequently transformed into the Ni/NiO-graph...

NiO-nanoflakes (NiO-NFs) grafted Ni-nanorod (Ni-NR) arrays stuck out of the porous anodic aluminum oxide (AAO) template are achieved by a combinatorial process of AAO-confined electrodeposition of Ni-NRs, selectively etching part of the AAO template to expose the Ni-NRs, wet-etching the exposed Ni-NRs in ammonia to obtain Ni(OH)2-NFs grafted onto the cone-shaped Ni-NRs, and annealing to transfo...

We are presenting our recent research results about the Ni-NiO nanoparticles on poly-(diallyldimethylammonium chloride)-modified graphene sheet (Ni-NiO/PDDA-G) nanocomposites prepared by the hydrothermal method at 90°C for 24 h. The Ni-NiO nanoparticles on PDDA-modified graphene sheets are measured by transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), and select...

Ni/NiO nanoflower modified reduced graphene oxide (rGO) nanocomposite (Ni/NiO-rGO) was introduced to screen printed electrode (SPE) for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO) hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, ...

We report a Ni-Cr/C electrocatalyst with unprecedented mass-activity for the hydrogen evolution reaction (HER) in alkaline electrolyte. The HER kinetics of numerous binary and ternary Ni-alloys and composite Ni/metal-oxide/C samples were evaluated in aqueous 0.1 M KOH electrolyte. The highest HER mass-activity was observed for Ni-Cr materials which exhibit metallic Ni as well as NiO x and Cr2O3...

In order to understand the resistance of passive films formed during corrosion processes, an analytical technique using x-ray diffraction was developed to examine the structure of metal in closest proximity to the metal / liquid interface. The in-situ structure at the metal liquid interface was examined for 90 % copper and 10 % nickel (90-10 Cu-Ni) in KOH solution at room temperature and at fou...

The electronic structure of NiO nanometric planar islands on highly oriented pyrolitic graphite has been studied by means of the Ni 2p and O 1s x-ray absorption spectra. The O 1s spectrum of the early stages of growth shows a double peak at threshold which is attributed to a splitting of the unoccupied Ni eg states. This spectrum is compared to previous results for 3 nm NiO nanoparticles which ...

In this work, we present a X-ray absorption spectroscopy (XAS) study of the growth of NiO on highly oriented pyrolytic graphite (HOPG). NiO as been grown by reactive evaporation of metallic Ni in an oxygen atmosphere (2× 10−5 Torr) at room temperature. We paid special attention to he study of the early stages of growth. Both, Ni 2p and O 1s core-level XAS spectra were measured. For large NiO co...

Photocatalysts are important for environmental cleanup of undesirable organic compounds and have potential applications for solar fuel generation either through water splitting or CO2 reduction [1]. It is now recognized that atomic level in-situ observations of catalytic materials are critical for understanding the structure-reactivity in catalysts. For photocatalysts, this requires that the sy...